A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Combustion oxygen requirement from balanced equation
Steps:
- Use combustion formula for CxHyOz: CxHyOz + (x + y/4 - z/2) O2 → x CO2 + (y/2) H2O, with x=3 for all.
- Calculate O2 for each: propane C3H8 (z=0) needs 3 + 8/4 = 5 O2.
- Propanoic acid C3H6O2 (z=2) needs 3 + 6/4 - 1 = 3.5 O2; propanone C3H6O (z=1) needs 3 + 6/4 - 0.5 = 4 O2.
- Propan-1-ol C3H8O (z=1) needs 3 + 8/4 - 0.5 = 4.5 O2, matching the given requirement.
Why D is correct:
- Propan-1-ol's formula C3H8O yields exactly 4.5 O2 molecules in the balanced combustion equation.
Why the others are wrong:
- A. Propane requires 5 O2 molecules, exceeding 4.5.
- B. Propanoic acid requires 3.5 O2 molecules, less than 4.5.
- C. Propanone requires 4 O2 molecules, not matching 4.5.
Final answer: D
Topic: An introduction to organic chemistry
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