A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Nucleophiles as electron pair donors
Steps:
- Recall that a nucleophile is a species that donates electrons to form a new bond.
- Examine the definition: nucleophiles provide a lone pair or pi electrons to an electrophile.
- Evaluate choices against this core property.
- Confirm B matches the universal trait, while others do not.
Why B is correct:
- By definition, every nucleophile donates a lone pair of electrons to an electron-deficient center, as in SN2 reactions where Nu: attacks C+.
Why the others are wrong:
- A: Nucleophiles attack electrophilic centers like carbocations, not necessarily double bonds (e.g., in SN1 reactions).
- C: Nucleophiles can be molecules like NH3 or OH-, not just single atoms.
- D: Nucleophiles can be neutral (e.g., H2O) or positively charged (e.g., RNH3+), not always negative.
Final answer: B
Topic: An introduction to organic chemistry
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