A Levels Chemistry (9701)•9701/12/O/N/18

Explanation
Hess's law applied to combustion enthalpy
Steps:
- Balance the equation: C₂H₅OH(l) + 3O₂(g) → 2CO₂(g) + 3H₂O(l).
- Use ΔH°_comb = [2ΔH°_f(CO₂) + 3ΔH°_f(H₂O)] - ΔH°_f(C₂H₅OH).
- Compute products: 2(-394) + 3(-286) = -788 - 858 = -1646 kJ mol⁻¹.
- Subtract reactants: -1646 - (-277) = -1369 kJ mol⁻¹.
Why B is correct:
- Not enough information; calculated value (-1369 kJ mol⁻¹) does not match any option.
Why the others are wrong:
- A is too small, ignoring multiple product molecules.
- C approximates wrong balancing (1 CO₂ + 3 H₂O).
- D approximates unbalanced reaction (1 CO₂ + 1 H₂O).
Final answer: Not enough information.
Topic: Chemical energetics
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