A Levels Chemistry (9701)•9701/12/O/N/18

Explanation
Dalton's Law of Partial Pressures at Constant Temperature
Steps:
- Calculate total initial amount of gas using PV (proportional to moles at constant T): for X, 12 kPa × 5 dm³ = 60 kPa·dm³; for Y, 6 kPa × 10 dm³ = 60 kPa·dm³.
- Add totals: 60 + 60 = 120 kPa·dm³.
- Final volume is 5 + 10 = 15 dm³.
- Final pressure = total PV / total V = 120 / 15 = 8 kPa.
Why A is correct:
- Dalton's law states total pressure equals sum of partial pressures; each partial pressure is initial P × (initial V / total V), yielding 4 kPa + 4 kPa = 8 kPa.
Why the others are wrong:
- B ignores volume difference, averaging pressures as (12 + 6)/2 = 9 kPa.
- C assumes equal volumes or misadds totals, possibly 150/15 = 10 kPa.
- D overestimates by using wrong total PV, like 165/15 = 11 kPa.
Final answer: A
Topic: States of matter
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