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A Levels Chemistry (9701)•9701/12/O/N/18
Question 5 from 9701/12/O/N/18

Explanation

Dalton's Law of Partial Pressures at Constant Temperature

Steps:

  • Calculate total initial amount of gas using PV (proportional to moles at constant T): for X, 12 kPa × 5 dm³ = 60 kPa·dm³; for Y, 6 kPa × 10 dm³ = 60 kPa·dm³.
  • Add totals: 60 + 60 = 120 kPa·dm³.
  • Final volume is 5 + 10 = 15 dm³.
  • Final pressure = total PV / total V = 120 / 15 = 8 kPa.

Why A is correct:

  • Dalton's law states total pressure equals sum of partial pressures; each partial pressure is initial P × (initial V / total V), yielding 4 kPa + 4 kPa = 8 kPa.

Why the others are wrong:

  • B ignores volume difference, averaging pressures as (12 + 6)/2 = 9 kPa.
  • C assumes equal volumes or misadds totals, possibly 150/15 = 10 kPa.
  • D overestimates by using wrong total PV, like 165/15 = 11 kPa.

Final answer: A

Topic: States of matter

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