A Levels Chemistry (9701)•9701/12/O/N/18

Explanation
Chromium reduction in redox reaction Steps:
- Examine oxidation states: In Na2CrO4, Cr is +6 (chromate ion: CrO4^2-, O is -2, so Cr + 6).
- In products, Cr2(SO4)3 shows Cr as +3 (SO4^2- is -2, so 2Cr + 3(-2) = 0, Cr = +3).
- Confirm reduction: Cr decreases from +6 to +3, gaining electrons.
- Balance with oxidation: Fe goes from +2 in FeSO4 to +3 in Fe2(SO4)3, but focus on Cr change.
Why B is correct:
- Reduction defined as gain of electrons or decrease in oxidation number; Cr(VI) to Cr(III) fits exactly per IUPAC redox rules.
Why the others are wrong:
- A: Describes oxidation of Fe(II), not the specified Cr reduction.
- C: Oxygen in chromate stays -2 in products; no direct reduction to H2O.
Final answer: B
Topic: Chemistry of transition elements
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