A Levels Chemistry (9701)•9701/12/O/N/18

Explanation
Mild oxidation of butan-2-one with KMnO₄ Steps:
- Identify Q as butan-2-one, CH₃C(O)CH₂CH₃, an unsymmetrical ketone.
- Note cold, dilute, acidified manganate(VII) acts as a mild oxidant targeting the terminal methyl in the ethyl group.
- Oxidation converts -CH₂CH₃ to -CH₂CH₂OH, preserving the carbonyl.
- Resulting product CH₃C(O)CH₂CH₂OH matches option C. Why C is correct:
- Cold, dilute, acidified KMnO₄ selectively oxidizes the primary carbon in the alkyl chain of methyl ketones to a primary alcohol, per standard organic oxidation rules. Why the others are wrong:
- A: Butan-2-one has no C=C bond for addition polymerization; repeat unit suggests vinyl monomer like methyl acrylate.
- B: Alpha-chlorination of ketones uses electrophilic mechanism with Cl₂/acid, not free radical.
- D: Alpha-bromination of ketones is electrophilic, not free radical with Br₂. Final answer: C
Topic: Carbonyl compounds
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