A Levels Chemistry (9701)•9701/12/O/N/18

Explanation
Properties distinguishing ethene monomer from polyethene polymer Steps:
- Empirical formula of ethene is CH₂; polyethene repeats -CH₂-CH₂- units, so also CH₂.
- Ethene is flammable gas; polyethene is solid plastic that burns but isn't typically a fuel source.
- Van der Waals forces depend on molecular size: small ethene molecules have weak forces (low boiling point, -104°C); long polyethene chains have strong forces (melts at ~115°C).
- Opposite of C would mean stronger forces in monomer, which contradicts molecular size effect.
Why C is correct:
- Van der Waals forces strengthen with increased surface area for interactions; polymers' long chains provide more contact than small monomers, per intermolecular force principles.
Why the others are wrong:
- A: Both share empirical formula CH₂, unchanged in addition polymerization.
- B: Polyethene can be combusted as fuel in waste-to-energy processes, though not conventional like gaseous ethene.
- D: Monomer's forces are weaker, not greater, due to smaller size.
Final answer: C
Topic: Polymerisation
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