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A Levels Chemistry (9701)•9701/12/O/N/18
Question 21 from 9701/12/O/N/18

Explanation

Counting σ Bonds in Molecular Structures

Steps:

  • Examine the diagram to identify all atoms and their bonding types (single, double, triple).
  • Count each single bond as 1 σ bond; each double bond as 1 σ bond (plus 1 π); each triple bond as 1 σ bond (plus 2 π).
  • Include σ bonds from C-H, O-H, or other terminal bonds.
  • Total the σ bonds across the entire molecule.

Why C is correct:

  • The structure features 18 σ bonds, matching the rule that every bonded atom pair has exactly one σ bond from end-to-end orbital overlap.

Why the others are wrong:

  • A: Undercounts by ignoring σ components in multiple bonds.
  • B: Misses a few single or multiple bond σ contributions.
  • D: Overcounts by treating π bonds as additional σ bonds.

Final answer: C

Topic: Chemical bonding

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