A Levels Chemistry (9701)•9701/11/O/N/18

Explanation
Claisen Condensation for Beta-Keto Ester Synthesis
Steps:
- Target molecule is 3-oxobutanoic acid (CH₃COCH₂COOH), a beta-keto acid.
- Beta-keto acids form via hydrolysis of beta-keto esters like ethyl acetoacetate (Y).
- Ethyl acetoacetate synthesizes from Claisen condensation of two ethyl acetate molecules (X).
- Thus, X is ethyl acetate (CH₃COOCH₂CH₃).
Why A is correct:
- A depicts ethyl acetate, the self-condensing ester in Claisen reaction yielding the beta-keto ester precursor per the mechanism: enolate attacks carbonyl, eliminating ethoxide.
Why the others are wrong:
- B (acetone): Lacks ester group needed for Claisen; used in haloform reaction instead.
- C (acetic acid): Cannot undergo Claisen without ester activation.
- D (ethyl malonate): Yields malonic ester derivatives, not acetoacetic acid analogs.
Final answer: A
Topic: Organic synthesis
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