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A Levels Chemistry (9701)•9701/14/M/J/25
Question 37 from 9701/14/M/J/25

Explanation

Stoichiometry of citric acid neutralization by sodium carbonate Steps:

  • Convert volume to dm³: 20 cm³ = 0.020 dm³.
  • Calculate moles of Na₂CO₃: 0.020 dm³ × 0.50 mol dm⁻³ = 0.010 mol.
  • Na₂CO₃ neutralizes 2 mol H⁺ per mol (Na₂CO₃ + 2H⁺ → 2Na⁺ + H₂O + CO₂), so total H⁺ = 2 × 0.010 = 0.020 mol.
  • Citric acid formula shows 3 COOH groups, providing 3 H⁺ per molecule, so moles citric acid = 0.020 / 3 ≈ 0.0067 mol. Not enough information: Exact number of H⁺ reacting (all 3 or fewer?) is ambiguous without specified titration conditions. Why B is correct: N/A—calculation yields ~0.007 mol, not matching any option precisely; B closest if assuming diprotic (0.010 mol, but still not 0.04). Why the others are wrong:
  • A: Assumes monoprotic citric acid (0.020 mol H⁺ = 0.020 mol acid).
  • C: Assumes ~0.10 mol Na₂CO₃ (e.g., 200 cm³ volume).
  • D: Assumes ~0.18 mol Na₂CO₃ (e.g., 360 cm³ volume).

Final answer: Not enough information.

Topic: Carboxylic acids and derivatives

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