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A Levels Chemistry (9701)•9701/14/M/J/25
Question 22 from 9701/14/M/J/25

Explanation

Nitrate thermal stability identifies Q as calcium; R is the hydroxide from successive reactions.

Steps:

  • Group 2 nitrates increase in thermal stability down the group: Ca(NO₃)₂ decomposes below Sr(NO₃)₂, while Ba(NO₃)₂ is more stable.
  • Q forms a nitrate less stable than Sr(NO₃)₂, so Q is calcium.
  • Flow diagram: first reaction is Q + O₂ → QO (oxide formation).
  • Second reaction: QO + H₂O → Q(OH)₂, so R is Ca(OH)₂.

Why B is correct:

  • Ca(OH)₂ forms via CaO + H₂O → Ca(OH)₂, the standard reaction for Group 2 oxides with water.

Why the others are wrong:

  • A. CaO is the intermediate from the first reaction, not R.
  • C. BaO is barium oxide, but Q is calcium.
  • D. Ba(OH)₂ is barium hydroxide, but Q is calcium.

Final answer: B

Topic: Group 2

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