A Levels Chemistry (9701)•9701/14/M/J/25

Explanation
Substance J is barium metal, identified by gas evolution and precipitate formation
Steps:
- Substance J + water produces gas (H2) and increases pH, indicating a reactive metal forming soluble hydroxide.
- Resulting solution contains Ba(OH)2, which is basic and soluble.
- Adding H2SO4 forms white BaSO4 precipitate, confirming Ba²⁺ ions.
- Only barium metal matches all reactions: Ba + 2H₂O → Ba(OH)₂ + H₂.
Why A is correct:
- Barium metal reacts with water to evolve H₂ gas and form soluble Ba(OH)₂ (pH rises); Ba(OH)₂ + H₂SO₄ → BaSO₄ (insoluble white precipitate, per solubility rules).
Why the others are wrong:
- B: Barium oxide + H₂O → Ba(OH)₂ (no gas evolved).
- C: Magnesium oxide + H₂O → Mg(OH)₂ (sparingly soluble, no gas); MgSO₄ is soluble (no precipitate).
- D: Identical to C (magnesium oxide).
Final answer: A
Topic: Group 2
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