A Levels Chemistry (9701)•9701/13/M/J/25

Explanation
α,β-Unsaturated aldehyde identification Steps:
- Fehling's solution detects reducing agents like aldehydes, producing red-brown Cu₂O precipitate.
- Cis-trans isomerism requires a carbon-carbon double bond with different substituents on each carbon.
- Compound P must be an aldehyde (for Fehling's test) with an internal C=C bond (for geometric isomerism).
- Thus, P is an α,β-unsaturated aldehyde like but-2-enal, which has E/Z isomers and reduces Fehling's.
Why D is correct:
- D (but-2-enal, CH₃CH=CHCHO) has a C=C bond enabling cis-trans isomers and an aldehyde group that reduces Cu²⁺ to Cu₂O.
Why the others are wrong:
- A (ethanal, CH₃CHO): Saturated aldehyde; no C=C for cis-trans isomerism.
- B (propanone, CH₃COCH₃): Ketone; does not reduce Fehling's and lacks C=C.
- C (propanal, CH₃CH₂CHO): Saturated aldehyde; no cis-trans isomerism.
Final answer: D
Topic: Carbonyl compounds
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