A Levels Chemistry (9701)•9701/13/M/J/25

Explanation
Nucleophilic substitution with cyanide for chain lengthening Steps:
- Identify reaction as SN2 on primary alkyl halide requiring CN⁻ nucleophile.
- Select reagent providing high CN⁻ concentration: KCN over HCN (weak acid, low dissociation).
- Choose solvent: polar protic like alcohol for SN2; avoid acids that protonate CN⁻ to HCN.
- Apply heat under reflux to ensure completion without loss of volatile products.
Why A is correct:
- KCN dissociates fully to CN⁻; dilute alcohol (ethanol) is polar protic solvent promoting SN2 per standard organic mechanisms.
Why the others are wrong:
- B: Dilute sulfuric acid protonates CN⁻ (CN⁻ + H⁺ → HCN), lowering nucleophile availability.
- C: HCN gives low CN⁻ concentration; sulfuric acid further suppresses ionization.
- D: HCN in ethanol maintains low CN⁻ levels, insufficient for efficient substitution.
Final answer: A
Topic: Halogen compounds
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