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A Levels Chemistry (9701)•9701/13/M/J/25
Question 26 from 9701/13/M/J/25

Explanation

Amide hydrolysis yields sodium carboxylate and ammonia

Steps:

  • Identify reaction as CH₃CONH₂ + NaOH → CH₃COONa + NH₃ (ethanethiol likely misstated as ethanamide).
  • Moles of CH₃COONa theoretically produced: 0.200 mol (1:1 stoichiometry).
  • Molar mass of CH₃COONa: 82 g/mol; theoretical mass: 0.200 × 82 = 16.4 g.
  • Actual mass at 80% yield: 16.4 × 0.80 = 13.12 g ≈ 13 g.

Why B is correct:

  • Matches calculated mass of S (CH₃COONa) after applying 80% yield to theoretical 16.4 g.

Why the others are wrong:

  • A: Underestimates yield (e.g., 50% would be ~8.2 g, not 80%).
  • C: Assumes ~92% yield (15/16.4 ≈ 0.91), exceeding 80%.
  • D: Theoretical mass without yield adjustment (16.4 g rounded).

Final answer: B

Topic: Nitrogen compounds

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