A Levels Chemistry (9701)•9701/13/M/J/25

Explanation
Ionic and atomic radii trends for isoelectronic species
Steps:
- Examine electron configurations: Na⁺, Ne, F⁻ all have 10 electrons (isoelectronic).
- For isoelectronic species, radius increases as nuclear charge (protons) decreases, weakening electron attraction.
- Na⁺ has 11 protons (smallest), Ne has 10 (medium), F⁻ has 9 (largest).
- Verify other options lack this increasing trend.
Why D is correct:
- Na⁺, Ne, F⁻ are isoelectronic; per the trend, ionic radius increases with decreasing effective nuclear charge (Zeff = protons - shielding), from Na⁺ (Zeff highest) to F⁻ (Zeff lowest).
Why the others are wrong:
- A: Neutral atoms N > O > F in size (decreases across period 2 due to increasing Zeff).
- B: Mg²⁺ (12 protons, 10 electrons) < Na⁺, so Na⁺ to Mg²⁺ decreases in size.
- C: O²⁻ (8 protons, 10 electrons) > F⁻, so Na⁺ < O²⁻ > F⁻, not increasing.
Final answer: D
Topic: The Periodic Table: chemical periodicity
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