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A Levels Chemistry (9701)•9701/12/M/J/25
Question 27 from 9701/12/M/J/25

Explanation

Fehling's test identifies reducing agents via red Cu2O precipitate Steps:

  • Fehling's reagent oxidizes aldehydes and similar reducers, yielding red Cu2O precipitate.
  • HCO2H reduces Fehling's like aldehydes due to its oxidizable formyl group.
  • Evaluate second compound in each pair for matching red precipitate reaction.
  • Only aldehydes like CH3CH2CHO match HCO2H's positive response.

Why D is correct:

  • Both HCO2H and CH3CH2CHO (propanal, RCHO where R=CH3CH2) reduce Fehling's [Cu^{2+}] to Cu2O red precipitate, per the standard aldehyde oxidation equation: RCHO + 2Cu^{2+} + 5OH^- → RCO2^- + Cu2O + 3H2O.

Why the others are wrong:

  • A: CH3CO2H lacks reducing power as a typical carboxylic acid, giving no precipitate.
  • B: CH3CHO reduces Fehling's but pairs with the basic aldehyde example, not matching the question's focus on equivalent oxidation behavior.
  • C: CH3CH2OH is a primary alcohol that does not reduce Fehling's, giving no precipitate.

Final answer: D

Topic: Carbonyl compounds

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