A Levels Chemistry (9701)•9701/11/M/J/25

Explanation
Termination products in free-radical bromination of ethane
Steps:
- Free-radical mechanism includes initiation (Br₂ → 2Br•), propagation (forming C₂H₅Br and HBr), and termination.
- Termination step: two ethyl radicals combine (2C₂H₅• → C₄H₁₀, butane).
- Termination step: two bromine radicals combine (2Br• → Br₂, bromine).
- Hydrogen bromide forms only in propagation, not termination.
Why C is correct:
- Butane and bromine are directly formed via radical coupling in termination steps, per the mechanism definition.
Why the others are wrong:
- A includes 2, but HBr arises from propagation (C₂H₆ + Br• → C₂H₅• + HBr), not as a listed termination product.
- B includes 2 but excludes 3, ignoring Br₂ regeneration in termination.
- D includes 2 but excludes 1, overlooking butane from ethyl radical dimerization.
Final answer: C
Topic: Hydrocarbons
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