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A Levels Chemistry (9701)•9701/11/M/J/25
Question 35 from 9701/11/M/J/25

Explanation

Percent yield via mass ratio; relative rate via leaving group ability Steps:

  • Compute percent yield for reaction 1: (12.3 g product / 18 g reactant) × 100 ≈ 68% (rounded to 70% in choices).
  • Identify reactions: Both tertiary halides undergo E2/SN1-E1 with hot aq NaOH, yielding 2-methylbut-2-ene (X).
  • Compare rates: Leaving group Br⁻ (reaction 1) departs faster than Cl⁻ (reaction 2) due to weaker C-Br bond and better stabilization.
  • Select option: 70% yield with reaction 1 faster matches data.

Why C is correct:

  • Aligns with mass-based yield calculation and SN1/E2 rate law emphasizing leaving group (Br > Cl).

Why the others are wrong:

  • A: Incorrect yield (41% mismatches 70% calculation).
  • B: Incorrect yield (41%) and relative rate (Cl⁻ poorer leaving group than Br⁻).
  • D: Incorrect relative rate (reaction 2 slower, not faster).

Final answer: C

Topic: Halogen compounds

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