A Levels Chemistry (9701)•9701/11/M/J/25

Explanation
Kc increases for endothermic reaction when temperature rises
Steps:
- Reaction is endothermic (ΔH = +58 kJ mol⁻¹), so forward direction absorbs heat.
- Kc rises from 1.5 × 10⁻³ to 1.7 × 10⁻³ mol dm⁻³, indicating shift toward products.
- Per Le Chatelier's principle, higher temperature favors endothermic direction, increasing Kc.
- Pressure changes do not alter Kc value, which depends only on temperature.
Why C is correct:
- Endothermic reactions have Kc that increases with temperature, as heat acts like a reactant (van't Hoff equation: ln K = -ΔH/RT + constant).
Why the others are wrong:
- A: Pressure increase shifts equilibrium left (fewer moles), but Kc remains unchanged at constant temperature.
- B: Pressure decrease shifts right, but Kc value is unaffected.
- D: Temperature decrease favors exothermic direction, decreasing Kc.
Final answer: C
Topic: Equilibria
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