A Levels Chemistry (9701)•9701/13/M/J/24

Explanation
Mass percentages from molar masses of ester hydrolysis products Steps:
- Ethyl ethanoate (CH₃COOCH₂CH₃) hydrolyses to ethanoic acid (CH₃COOH) and ethanol (CH₃CH₂OH); basic conditions with NaOH typically yield salt, but products are often considered as acid after acidification in such analyses.
- Molar mass of ethanoic acid: 60 g/mol; ethanol: 46 g/mol.
- Total molar mass of organic products: 60 + 46 = 106 g/mol.
- Percentage of ethanol: (46/106) × 100 ≈ 43%; ethanoic acid: (60/106) × 100 ≈ 57%.
Why C is correct:
- 42% and 57% are the closest match to calculated values of ~43% ethanol and ~57% ethanoic acid based on molar mass ratio.
Why the others are wrong:
- A: 32% and 67% deviate too far from 43–57% ratio, possibly confusing salt masses.
- B: 38% and 61% underestimate ethanol percentage.
- D: 50% and 50% ignores unequal molar masses of products.
Final answer: C
Topic: Carboxylic acids and derivatives
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