A Levels Chemistry (9701)•9701/13/M/J/24

Explanation
Salt formation yields highest molar mass product
Steps:
- Ethanoic acid is CH₃COOH (Mᵣ=60).
- React with each reagent to identify main organic product.
- Compute Mᵣ for each: A gives CH₃CH₂OH (46); B gives (CH₃COO)₂Mg (142); C gives CH₃COOK (98); D gives CH₃COOCH(CH₃)₂ (102).
- Select highest Mᵣ product.
Why B is correct:
- Magnesium hydride (MgH₂) reacts as: 2CH₃COOH + MgH₂ → (CH₃COO)₂Mg + 2H₂, forming magnesium ethanoate with Mᵣ=142 (C₄H₆MgO₄).
Why the others are wrong:
- A: LiAlH₄ reduces acid to ethanol (CH₃CH₂OH, Mᵣ=46).
- C: K₂CO₃ neutralizes to potassium ethanoate (CH₃COOK, Mᵣ=98).
- D: Propan-2-ol esterifies to isopropyl ethanoate (Mᵣ=102).
Final answer: B
Topic: Carboxylic acids and derivatives
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