A Levels Chemistry (9701)•9701/13/M/J/24

Explanation
Acid-base neutralization producing polar products
Steps:
- Write the reaction: NH₄Cl + NaOH → NH₃ + NaCl + H₂O in aqueous solution.
- Identify key products: NH₃ (ammonia) and H₂O (water) as molecular products.
- Assess polarity: Both NH₃ (trigonal pyramidal, μ ≈ 1.47 D) and H₂O (bent, μ ≈ 1.85 D) are polar.
- Evaluate options against reaction details.
Why A is correct:
- The reaction yields NH₃ and H₂O, two distinct polar molecules due to their asymmetric shapes and electronegativity differences (polarity defined by dipole moment > 0 D).
Why the others are wrong:
- B: Bond angle changes from 109.5° in tetrahedral NH₄⁺ to 107° in trigonal pyramidal NH₃.
- C: NH₄⁺ acts as an acid by donating H⁺ to OH⁻, per Brønsted-Lowry definition.
- D: Nitrogen oxidation state remains -3 in both NH₄⁺ and NH₃ (calculated as N surrounded by four H at +1 each).
Final answer: A
Topic: Nitrogen and sulfur
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