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A Levels Chemistry (9701)•9701/13/M/J/24
Question 23 from 9701/13/M/J/24

Explanation

Acid-base neutralization producing polar products

Steps:

  • Write the reaction: NH₄Cl + NaOH → NH₃ + NaCl + H₂O in aqueous solution.
  • Identify key products: NH₃ (ammonia) and H₂O (water) as molecular products.
  • Assess polarity: Both NH₃ (trigonal pyramidal, μ ≈ 1.47 D) and H₂O (bent, μ ≈ 1.85 D) are polar.
  • Evaluate options against reaction details.

Why A is correct:

  • The reaction yields NH₃ and H₂O, two distinct polar molecules due to their asymmetric shapes and electronegativity differences (polarity defined by dipole moment > 0 D).

Why the others are wrong:

  • B: Bond angle changes from 109.5° in tetrahedral NH₄⁺ to 107° in trigonal pyramidal NH₃.
  • C: NH₄⁺ acts as an acid by donating H⁺ to OH⁻, per Brønsted-Lowry definition.
  • D: Nitrogen oxidation state remains -3 in both NH₄⁺ and NH₃ (calculated as N surrounded by four H at +1 each).

Final answer: A

Topic: Nitrogen and sulfur

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