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A Levels Chemistry (9701)•9701/12/M/J/24
Question 39 from 9701/12/M/J/24

Explanation

Addition Polymerization Mechanism

Steps:

  • Identify monomer Z as an alkene with a C=C double bond suitable for addition.
  • Recall that addition polymers form by breaking the double bond, linking monomers via free radical or chain reaction without eliminating small molecules.
  • Determine the repeating unit: the opened alkene structure connected head-to-tail.
  • Compare choices to find the linear chain with Z's modified unit.

Why D is correct:

  • D depicts the repeating -[CH₂-CHZ]- unit, matching the addition polymerization definition where the double bond becomes a single bond in the chain.

Why the others are wrong:

  • A shows ester linkages, typical of condensation polymers like polyesters.
  • B has branched structure, not the linear chain from simple addition.
  • C retains the double bond, which breaks in actual polymerization.

Final answer: D

Topic: Polymerisation

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