A Levels Chemistry (9701)•9701/12/M/J/24

Explanation
Base-neutralizing substances lower pH of NaOH solution
Steps:
- Sodium reacts with water: 2Na + 2H₂O → 2NaOH + H₂, forming basic solution Y (pH > 7).
- Adding X lowers pH, so X must provide H⁺ or consume OH⁻.
- MgCl₂ → Mg²⁺ + 2Cl⁻; Mg²⁺ hydrolyzes (Mg(H₂O)₆²⁺ ⇌ Mg(H₂O)₅OH⁺ + H⁺), generating acidity.
- Al(OH)₃ + OH⁻ → [Al(OH)₄]⁻, dissolving in base and consuming OH⁻ to reduce pH.
Why A is correct:
- MgCl₂ and Al(OH)₃ (assuming A lists these) both acidify or neutralize the basic Y via hydrolysis or amphoteric reaction.
Why the others are wrong:
- B: MgCl and OH are invalid/incomplete; no pH effect possible.
- C: NaCl neutral (no ions affect pH); Al OH incomplete.
- D: NaCl neutral; KO nonexistent compound.
Final answer: A
Topic: Equilibria
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