A Levels Chemistry (9701)•9701/13/M/J/23

Explanation
Titration curve identifies weak base in flask titrated by strong acid
Steps:
- Analyze curve: starts at high pH (~11), gradual decrease, sharp drop at equivalence, then low pH.
- X in flask sets initial high pH, indicating base; gradual pre-equivalence drop suggests weak base.
- Y from burette causes sharp pH change, indicating strong acid.
- Match to options: weak base (ammonia) with strong acid (nitric).
Why A is correct:
- Ammonia (weak base, pKb ~4.75) titrated by nitric acid (strong acid) produces curve with buffer region before equivalence and sharp pH drop, per Henderson-Hasselbalch equation.
Why the others are wrong:
- B: Ethanoic acid is weak; weak-weak titration lacks sharp equivalence point.
- C: Not provided; insufficient information.
- D: KOH is strong base; curve would start at higher pH (~13) with immediate sharp drop, no buffer region.
Final answer: A
Topic: Equilibria
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