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A Levels Chemistry (9701)•9701/13/M/J/23
Question 14 from 9701/13/M/J/23

Explanation

Oxidation state of nitrogen in nitrite ion

Steps:

  • In NO₂⁻, each O is -2 (total -4); ion charge -1, so N oxidation state = +3.
  • In NH₄F (NH₄⁺ ion), each H is +1 (total +4); ion charge +1, so N = -3.
  • In N₂O, O is -2; neutral molecule, two N total +2 (average +1).
  • In NO₃⁻, three O total -6; ion charge -1, so N = +5; in NF₃, three F total -3; neutral, so N = +3.

Why D is correct:

  • NF₃ follows the rule that F is always -1; thus, N must be +3 to balance the neutral molecule, identical to NO₂⁻.

Why the others are wrong:

  • A: NH₄⁺ has N at -3 due to H's +1 oxidation states.
  • B: N₂O's neutrality requires N atoms to average +1, not +3.
  • C: NO₃⁻ has N at +5 from three O's -2 each.

Final answer: D

Topic: Nitrogen and sulfur

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