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A Levels Chemistry (9701)•9701/12/M/J/23
Question 38 from 9701/12/M/J/23

Explanation

Hydrolysis reactions producing specific carboxylic acids Steps:

  • Identify structures: propyl ethanoate (CH₃COOC₃H₇), ethyl ethanoate (CH₃COOC₂H₅), propanenitrile (CH₃CH₂CN), ethanenitrile (CH₃CN).
  • Recall products: alkaline ester hydrolysis gives carboxylate salt; acid ester/nitrile hydrolysis gives carboxylic acid.
  • Check A: alkaline hydrolysis yields CH₃COO⁻ (ethanoate salt).
  • Check B, C, D: acid hydrolysis yields CH₃COOH (ethanoic acid) for B and D; CH₃CH₂COOH (propanoic acid) for C.

Why C is correct:

  • Acid hydrolysis of nitriles follows RCN + 2H₂O + HCl → RCOOH + NH₄Cl; for propanenitrile (R = CH₃CH₂), it yields propanoic acid.

Why the others are wrong:

  • A: Alkaline hydrolysis of propyl ethanoate gives sodium ethanoate (CH₃COONa), requiring acidification for the acid.
  • B: Acid hydrolysis of ethyl ethanoate gives ethanoic acid (CH₃COOH).
  • D: Acid hydrolysis of ethanenitrile gives ethanoic acid (CH₃COOH).

Final answer: C

Topic: Carboxylic acids and derivatives

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