A Levels Chemistry (9701)•9701/12/M/J/23

Explanation
Hydrolysis reactions producing specific carboxylic acids Steps:
- Identify structures: propyl ethanoate (CH₃COOC₃H₇), ethyl ethanoate (CH₃COOC₂H₅), propanenitrile (CH₃CH₂CN), ethanenitrile (CH₃CN).
- Recall products: alkaline ester hydrolysis gives carboxylate salt; acid ester/nitrile hydrolysis gives carboxylic acid.
- Check A: alkaline hydrolysis yields CH₃COO⁻ (ethanoate salt).
- Check B, C, D: acid hydrolysis yields CH₃COOH (ethanoic acid) for B and D; CH₃CH₂COOH (propanoic acid) for C.
Why C is correct:
- Acid hydrolysis of nitriles follows RCN + 2H₂O + HCl → RCOOH + NH₄Cl; for propanenitrile (R = CH₃CH₂), it yields propanoic acid.
Why the others are wrong:
- A: Alkaline hydrolysis of propyl ethanoate gives sodium ethanoate (CH₃COONa), requiring acidification for the acid.
- B: Acid hydrolysis of ethyl ethanoate gives ethanoic acid (CH₃COOH).
- D: Acid hydrolysis of ethanenitrile gives ethanoic acid (CH₃COOH).
Final answer: C
Topic: Carboxylic acids and derivatives
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