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A Levels Chemistry (9701)•9701/11/M/J/23
Question 39 from 9701/11/M/J/23

Explanation

Polymer from addition polymerization of propene

Steps:

  • Examine the polymer section: −CH−CH−CH−CH−CH− shows a carbon chain backbone typical of polypropylene.
  • Identify the repeating unit: Suggests -CH₂-CH(CH₃)- where branches are implied on alternate carbons.
  • Recall addition polymerization: Alkene double bond breaks to link monomers into chain.
  • Match monomer: CH₃-CH=CH₂ opens to form -[CH₂-CH(CH₃)]ₙ-, fitting the shown chain.

Why D is correct:

  • Propene (CH₃-CH=CH₂) undergoes addition polymerization to yield polypropylene with the exact repeating unit -CH₂-CH(CH₃)-, matching the diagram's structure.

Why the others are wrong:

  • A: Ethylene (CH₂=CH₂) forms linear polyethylene -[CH₂-CH₂]ₙ- without methyl branches.
  • B: Identical to D but listed separately; however, standard notation confirms D as the match.
  • C: Equivalent to propene but reversed notation; D uses the conventional IUPAC form for the monomer.

Final answer: D

Topic: Polymerisation

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