A Levels Chemistry (9701)•9701/11/M/J/23

Explanation
Free Radical Chain Reaction Steps:
- Identify reactions involving initiation (radical formation), propagation (radical chain), and termination (radical recombination).
- Examine each equation for halogenation, a classic free radical process.
- Rule out ionic or nucleophilic substitutions lacking chain steps.
- Confirm A matches radical chlorination of alkanes.
Why A is correct:
- Chlorination of ethyl chloride (or alkane analog) follows free radical mechanism with Cl• initiation by light/heat, propagation via H-abstraction and Cl-addition, and termination by radical coupling, per chain reaction theory.
Why the others are wrong:
- B: Nucleophilic substitution (SN2) of alkyl bromide with OH⁻, no radicals.
- C: Acid-catalyzed SN1/SN2 conversion of alcohol to bromide, ionic mechanism.
- D: Unclear reaction (possibly cyanohydrin, but invalid for alcohol); lacks chain steps.
Final answer: A
Topic: Hydrocarbons
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