A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Weighted average of isotope masses
Steps:
- Determine percentage of 32S: 100% - 4.2% - 2.8% = 93%.
- Calculate contributions: (93 × 32) + (4.2 × 34) + (2.8 × 36) = 2976 + 142.8 + 100.8 = 3219.6.
- Divide by 100 to get average mass: 3219.6 / 100 = 32.196.
- Round to one decimal place: 32.2.
Why B is correct:
- Relative atomic mass is the weighted average of isotope masses by abundance, yielding 32.2 here.
Why the others are wrong:
- A: Underestimates heavier isotope contributions by about 0.1.
- C: Ignores dominant 32S, averaging only heavier isotopes.
- D: Overweights heavier isotopes, exceeding calculated value.
Final answer: B
Topic: Atomic structure
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