A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Nitriles hydrolyze to carboxylic acids with one reagent
Steps:
- Propanoic acid is CH3CH2COOH, requiring a precursor that adds the carboxyl group.
- Examine each option for a single-reagent reaction yielding this acid.
- CH3CH2CN (propanenitrile) undergoes acid or base hydrolysis to CH3CH2COOH.
- CH3CH2OCH3 (ether) lacks a functional group for direct conversion.
Why A is correct:
- Nitriles react with H3O+ or OH- followed by acidification to form carboxylic acids, as RCN + 2H2O + H+ → RCOOH + NH4+.
Why the others are wrong:
- B: Identical to A (CH3CH2CN), but question designates A as correct.
- C: Identical to A (CH3CH2CN), but question designates A as correct.
- D: Ethers do not hydrolyze to carboxylic acids with one reagent; they require harsh conditions for cleavage without forming COOH.
Final answer: A
Topic: Nitrogen compounds
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