A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Determine C5H10 formula and count alkene isomers Steps:
- Molar volume at room conditions is 24 dm³/mol; moles of 10 g Y = 3.4 / 24 = 0.1417 mol; molar mass = 10 / 0.1417 ≈ 70 g/mol, so Y is C5H10.
- Decolorizes Br2, confirming unsaturation (alkene); excludes saturated hydrocarbons like cyclopentane.
- Acyclic alkene structural isomers: 1-pentene, 2-pentene, 2-methyl-1-butene, 3-methyl-1-butene, 2-methyl-2-butene.
- Include stereoisomers: 2-pentene has E and Z forms; total 6 isomers.
Why C is correct:
- C5H10 alkenes have 5 structural isomers, with 2-pentene adding 2 stereoisomers for 6 total, per IUPAC nomenclature.
Why the others are wrong:
- A: Counts only 4 structural isomers, ignoring stereoisomerism.
- B: Counts 5, omitting one stereoisomer of 2-pentene.
- D: Counts 7, including saturated cyclopentane that does not decolorize Br2.
Final answer: C
Topic: Hydrocarbons
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