A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Thermal decomposition of Group 2 nitrate to oxide residue Steps:
- Reaction: M(NO3)2 → MO + 2NO2 + ½O2; residue is MO.
- Molar mass of M(NO3)2 = M + 124; molar mass of MO = M + 16.
- Ratio of residue mass to initial mass = (M + 16)/(M + 124) = 3.7/4 = 0.925.
- Solve 0.925(M + 124) = M + 16 → M ≈ 1316 (does not match any Group 2 metal).
Why B is correct:
- Not enough information (calculated M does not match calcium or any option).
Why the others are wrong:
- A. Barium (M=137) gives ratio 153/261 ≈ 0.586; expected residue 2.3 g.
- C. Magnesium (M=24) gives ratio 40/148 ≈ 0.270; expected residue 1.1 g.
- D. Strontium (M=88) gives ratio 104/212 ≈ 0.491; expected residue 2.0 g.
Final answer: Not enough information.
Topic: Group 2
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