A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Solubility differences in group 2 hydroxides and sulfates
Steps:
- NaOH reacts with MgCl₂ to form insoluble Mg(OH)₂ white precipitate.
- NaOH reacts with BaCl₂ to form soluble Ba(OH)₂ colourless solution.
- Excess H₂SO₄ dissolves Mg(OH)₂ into soluble MgSO₄ colourless solution.
- Excess H₂SO₄ reacts with Ba(OH)₂ to form insoluble BaSO₄ white precipitate.
Why B is correct:
- B matches observations: colourless solution for MgCl₂ (MgSO₄ soluble) and white precipitate for BaCl₂ (BaSO₄ insoluble), per solubility rules for group 2 compounds.
Why the others are wrong:
- A: Predicts solutions for both, but ignores BaSO₄ precipitation.
- C: Reverses results; Mg(OH)₂ dissolves, while BaSO₄ forms precipitate.
- D: Predicts precipitates for both, but MgSO₄ remains soluble.
Final answer: B
Topic: Group 2
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