A Levels Chemistry (9701)•9701/13/M/J/22

Explanation
Redox analysis of NH₄NO₃ decomposition
Steps:
- Balanced equation: NH₄NO₃ → N₂O + 2H₂O.
- Oxidation states of N: -3 in NH₄⁺, +5 in NO₃⁻; in N₂O, one N at +1 and one at -1.
- NH₄⁺ (N from -3 to -1/+1) loses electrons, acting as reducing agent.
- NO₃⁻ (N from +5 to -1/+1) gains electrons, acting as oxidizing agent.
- N in same compound changes from -3 and +5 to +1 and -1, confirming disproportionation.
Why B is correct:
- Statements 1 and 2 identify correct redox roles (reducing agent loses e⁻, oxidizing agent gains e⁻); 3 matches disproportionation definition where same element is both oxidized and reduced.
Why the others are wrong:
- A includes incorrect 4 (likely false, e.g., not thermal decomposition type or similar).
- C omits valid 1 and 2, includes wrong 4.
- D excludes valid 1 and 2.
Final answer: B
Topic: Nitrogen and sulfur
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