A Levels Chemistry (9701)•9701/12/M/J/22

Explanation
Compound with both carbonyl and reducing properties
Steps:
- 2,4-DNP reagent forms a yellow precipitate with aldehydes and ketones via hydrazone formation.
- Fehling's reagent gives a red precipitate with reducing agents like aldehydes or aldoses that reduce Cu²⁺ to Cu₂O.
- Identify the option containing an aldehyde group, which tests positive for both.
- Option B (e.g., acetaldehyde) has an aldehydic -CHO group meeting both criteria.
Why B is correct:
- Aldehydes form 2,4-dinitrophenylhydrazones with 2,4-DNP and reduce Fehling's via oxidation of the aldehydic hydrogen.
Why the others are wrong:
- A (ketone like acetone): Forms DNP precipitate but does not reduce Fehling's as ketones lack aldehydic hydrogen.
- C (alcohol like ethanol): Lacks carbonyl, so no DNP reaction and not reducing for Fehling's.
- D (non-reactive like hydrocarbon): No functional groups for either test.
Final answer: B
Topic: Carbonyl compounds
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