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A Levels Chemistry (9701)•9701/11/M/J/22
Question 37 from 9701/11/M/J/22

Explanation

Ester hydrolysis yields carboxylic acid and alcohol Steps:

  • Hydrolysis of an ester RCOOR' produces RCOOH and R'OH.
  • Ethanoic acid is CH₃COOH, so the acyl group is CH₃C(O)-.
  • Butan-2-ol is CH₃CH(OH)CH₂CH₃, so the alkyl group is -CH(CH₃)CH₂CH₃.
  • The ester formula is CH₃CO₂CH(CH₃)CH₂CH₃, matching option B.

Why B is correct:

  • B is the ester of ethanoic acid and butan-2-ol; by ester hydrolysis definition, it yields CH₃COOH and CH₃CH(OH)CH₂CH₃.

Why the others are wrong:

  • A is butan-2-one (ketone); ketones do not undergo hydrolysis to give alcohol and carboxylic acid.
  • C is methyl propanoate; hydrolysis gives propanoic acid (CH₃CH₂COOH) and methanol (CH₃OH).
  • D is propyl ethanoate; hydrolysis gives ethanoic acid (CH₃COOH) and propan-1-ol (CH₃CH₂CH₂OH).

Final answer: B

Topic: Carboxylic acids and derivatives

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