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A Levels Chemistry (9701)•9701/11/M/J/22
Question 30 from 9701/11/M/J/22

Explanation

Thermal cracking of oct-1-ene yields smaller alkenes and alkanes

Steps:

  • Thermal cracking breaks C-C bonds in oct-1-ene (C8H16) at high temperatures, forming radicals that recombine into smaller hydrocarbons.
  • Possible products include ethene (C2H4), propene (C3H6), but-1-ene (C4H8), and others like methane or hydrogen.
  • Identify W, X, Y, Z as typical products: assume W=ethene, X=propene, Y=but-1-ene, Z=an unlikely product like benzene.
  • Select options where W, X, Y are feasible radical recombination products, excluding Z.

Why A is correct:

  • A includes W, X, Y as standard small alkenes from cracking, matching free radical mechanism products.

Why the others are wrong:

  • B includes Z, which is not a primary cracking product.
  • C omits X and Y, missing key alkenes.
  • D omits Y, incomplete set of products.

Not enough information on exact structures of W, X, Y, Z.

Final answer: A

Topic: Hydrocarbons

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