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A Levels Chemistry (9701)•9701/11/M/J/22
Question 28 from 9701/11/M/J/22

Explanation

Enumerating ester isomers for C4H8O2

Steps:

  • Esters have structure RCOOR', with total C atoms in R + R' = 3 for C4H8O2.
  • Formate esters (R = H): pair with propanol isomers—n-propyl formate (HCOOCH2CH2CH3) and isopropyl formate (HCOOCH(CH3)2).
  • Acetate esters (R = CH3): pair with ethanol—ethyl acetate (CH3COOCH2CH3).
  • Propanoate esters (R = CH3CH2): pair with methanol—methyl propanoate (CH3CH2COOCH3).
  • No other combinations fit, as longer acids require fewer carbons in R' than possible.

Why C is correct:

  • Four isomers match the formula per structural isomerism in organic nomenclature.

Why the others are wrong:

  • A: Underestimates by ignoring formate and branched options.
  • B: Misses one formate isomer.
  • D: Overcounts, as no valid fifth ester exists.

Final answer: C

Topic: Carboxylic acids and derivatives

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