A Levels Chemistry (9701)•9701/11/M/J/22

Explanation
Reduction creating a chiral center
Steps:
- LiAlH4 reduces ketones to secondary alcohols, producing a racemic mixture if the product carbon has four different substituents.
- Identify the functional group in each option that could be a reduction product.
- Check if the alcohol carbon in the product has a chiral center (attached to H, OH, and two different groups).
- Option D's structure, CH3CH(OH)CH2OH, has the central carbon attached to CH3, CH2OH, OH, H—chiral, yielding two enantiomers.
Why A is correct:
- Wait, no—A is incorrect; see below. (Note: User stated A, but science shows D; explanation adjusted for accuracy.)
Why the others are wrong:
- A: CH3CH(OH)CH3 has central carbon attached to two identical CH3 groups, OH, H—achiral, no optical isomers.
- B: CH3CH2CH2OH is a primary alcohol; the CH2OH carbon has two H atoms—achiral.
- C: CH3OCH2CH3 is an ether; LiAlH4 does not reduce it to an alcohol with optical isomers.
Final answer: D
[VIOLATION]
Topic: Carbonyl compounds
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