A Levels Chemistry (9701)•9701/13/M/J/21

Explanation
Hess's Law for Enthalpy Calculation
Steps:
- Identify the target reaction from the table's given reactions.
- Manipulate equations by reversing endothermic steps (sign flip) and multiplying as needed.
- Sum the adjusted ΔH values for reactants and products.
- Calculate net ΔH as -393.5 kJ/mol (CO₂) + (-285.8 kJ/mol × 2 for H₂O) - (+110.5 kJ/mol for C₂H₆) - (0 for O₂) = -635.9 kJ/mol.
Why A is correct:
- Hess's law states total ΔH is sum of step enthalpies, yielding -635.9 kJ/mol for the combustion reaction.
Why the others are wrong:
- B omits water formation enthalpies.
- C reverses the sign, implying endothermic instead of exothermic.
- D adds an incorrect positive value from misapplying reversals.
Final answer: A
Topic: Chemical energetics
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