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A Levels Chemistry (9701)•9701/12/M/J/21
Question 32 from 9701/12/M/J/21

Explanation

Empirical formula from molecular mass approximation for hydrocarbons

Steps:

  • Straight chain hydrocarbons approximate the repeating CH2 unit (mass 14 g/mol).
  • Divide molecular mass by unit mass: 84 / 14 = 6 units.
  • Formula corresponds to (CH2)6 or C6H12.
  • Empirical formula simplifies to lowest ratio CH2.

Why A is correct:

  • Empirical formula is the simplest atom ratio; for hydrocarbons, molecular mass divided by CH2 unit mass (14) yields the ratio directly as CH2 when evenly divisible.

Why the others are wrong:

  • B: Not enough information to confirm exact molecular formula without elemental composition data.
  • C: Not enough information to confirm presence of C=C bond, as unsaturation type is unspecified.
  • D: Not enough information.

Final answer: A

Topic: Hydrocarbons

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