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A Levels Chemistry (9701)•9701/12/M/J/21
Question 13 from 9701/12/M/J/21

Explanation

Identifying L as Na and M as Cl from Period 3 properties

Steps:

  • Oxide of L solid with giant structure and chloride unreactive with water identifies L as Na: Na₂O is giant ionic lattice, NaCl dissolves without hydrolysis.
  • Only Ar has lower melting point than M identifies M as Cl: Cl₂ has second-lowest mp (-101°C) in Period 3.
  • Compound of L (Na) and M (Cl) is NaCl, an ionic solid.
  • NaCl mp (801°C) exceeds Cl₂ mp, but fits as the specified compound of L and M.

Why C is correct:

  • NaCl is the formula for the ionic compound of Na (L) and Cl (M), per ionic bonding rules for metal-nonmetal.

Why the others are wrong:

  • A. Al₂S3 uses Al (whose Cl reacts with water) and S, not L/M.
  • B. MgS uses Mg (possible L but M=S has multiple lower mps) and S.
  • D. PCl₃ uses P (oxide molecular, not giant; Cl reacts with water) and Cl.

Final answer: C

Topic: The Periodic Table: chemical periodicity

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