A Levels Chemistry (9701)•9701/12/M/J/21

Explanation
Identifying L as Na and M as Cl from Period 3 properties
Steps:
- Oxide of L solid with giant structure and chloride unreactive with water identifies L as Na: Na₂O is giant ionic lattice, NaCl dissolves without hydrolysis.
- Only Ar has lower melting point than M identifies M as Cl: Cl₂ has second-lowest mp (-101°C) in Period 3.
- Compound of L (Na) and M (Cl) is NaCl, an ionic solid.
- NaCl mp (801°C) exceeds Cl₂ mp, but fits as the specified compound of L and M.
Why C is correct:
- NaCl is the formula for the ionic compound of Na (L) and Cl (M), per ionic bonding rules for metal-nonmetal.
Why the others are wrong:
- A. Al₂S3 uses Al (whose Cl reacts with water) and S, not L/M.
- B. MgS uses Mg (possible L but M=S has multiple lower mps) and S.
- D. PCl₃ uses P (oxide molecular, not giant; Cl reacts with water) and Cl.
Final answer: C
Topic: The Periodic Table: chemical periodicity
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