A Levels Chemistry (9701)•9701/12/M/J/21

Explanation
Hydrolysis of SiCl₄ produces acid and insoluble silica
Steps:
- SiCl₄ reacts with cold water via hydrolysis: SiCl₄ + 4H₂O → Si(OH)₄ + 4HCl.
- HCl dissociates in water, releasing H⁺ ions to form an acidic solution.
- Si(OH)₄ (silicic acid) is insoluble in cold water and forms a gelatinous precipitate.
- The mixture is thus acidic with a white precipitate of silica gel.
Why B is correct:
- The reaction yields HCl (acidic) and insoluble Si(OH)₄ (precipitate), per the hydrolysis equation.
Why the others are wrong:
- A: Precipitate of Si(OH)₄ forms, contrary to "no precipitate."
- C: Solution is acidic from HCl, not neutral.
- D: Solution is acidic from HCl, not neutral.
Final answer: B
Topic: The Periodic Table: chemical periodicity
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