A Levels Chemistry (9701)•9701/11/M/J/21

Explanation
Stoichiometry of propane combustion using gas volumes
Steps:
- Balanced equation: C₃H₈(g) + 5O₂(g) → 3CO₂(g) + 4H₂O(l)
- Moles of propane: 12 dm³ / 24 dm³ mol⁻¹ = 0.5 mol (room conditions ≈ 24 dm³/mol)
- Moles of O₂ required: 0.5 mol × 5 = 2.5 mol
- Mass of O₂: 2.5 mol × 32 g mol⁻¹ = 80 g
Why B is correct:
- The 5:1 molar ratio in the balanced combustion equation, combined with Avogadro's law for gas volumes, yields exactly 80 g of O₂ for 0.5 mol propane.
Why the others are wrong:
- A: Assumes incorrect 4:1 O₂:propane ratio, yielding 64 g (rounded to 60 g).
- C: Calculates for 1 mol propane (120 g O₂), double the required amount.
- D: Uses 24 dm³/mol but for 1 mol propane with excess (160 g O₂).
Final answer: B
Topic: Hydrocarbons
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