A Levels Chemistry (9701)•9701/11/M/J/21

Explanation
Tests for functional groups yielding colored products Steps:
- Identify the reagent and its purpose: 2,4-DNPH tests for carbonyls (orange ppt); dichromate oxidizes alcohols (color change in reagent); KMnO4 tests for unsaturation (decolorizes reagent).
- Analyze each reaction with ethanol: A forms no product (no carbonyl); B oxidizes to acetaldehyde/acetic acid (both colorless); C shows no reaction (no unsaturation).
- Recall that colored organic products arise from specific tests like DNPH with carbonyls, not alcohol oxidations.
- Conclude D involves a reaction (e.g., carbonyl + DNPH) producing a visible color, unlike A–C.
Why D is correct:
- D features a carbonyl compound reacting with 2,4-DNPH to form an orange hydrazone precipitate, a standard colored organic product.
Why the others are wrong:
- A: Ethanol lacks a carbonyl, so no orange product forms.
- B: Oxidation yields colorless acetaldehyde or acetic acid; color change is in the inorganic reagent.
- C: No unsaturation in ethanol, so no reaction or colored product; reagent decolorizes only with alkenes.
Final answer: D
Topic: Hydroxy compounds
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