A Levels Chemistry (9701)•9701/11/M/J/21

Explanation
Bond strength influences reactivity of geminal dihalides
Steps:
- Identify structures: 1,1-difluoroethane (CH₃CHF₂) and 1,1-dichloroethane (CH₃CHCl₂).
- Recall reactivity trend in haloalkanes: depends on halogen-carbon bond strength for reactions like substitution or elimination.
- Compare bond energies: C-F (485 kJ/mol) exceeds C-Cl (328 kJ/mol).
- Conclude difluoro compound has stronger bonds, reducing reactivity.
Why A is correct:
- Bond dissociation energy data shows stronger C-F bonds require more energy to break, decreasing reactivity per organic chemistry principles.
Why the others are wrong:
- B: Not enough information; polarity depends on dipole moment, which is present but context unclear.
- C: Not enough information; bond strength comparison is standard, but question ambiguity on intent.
- D: Incomplete statement provided.
Final answer: A
Topic: Halogen compounds
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