A Levels Chemistry (9701)•9701/11/M/J/21

Explanation
Amphoteric oxide of Period 3 element
Steps:
- Period 3 elements form oxides; Y is solid and reacts with hot NaOH to place X in anion, showing acidic/amphoteric nature.
- Y also reacts with hot conc. HCl to place X in anion, showing basic/amphoteric nature.
- Thus, Y is amphoteric; in Period 3, only Al₂O₃ fits (Al in group 13).
- Al has outer configuration 3s² 3p¹, so 1 p electron.
Why B is correct:
- Al (3p¹) forms Al₂O₃, which reacts with NaOH to [Al(OH)₄]⁻ and with conc. HCl to [AlCl₄]⁻, placing Al in anions per amphoteric definition.
Why the others are wrong:
- A (0): Mg (group 2, 3s²) forms basic MgO; reacts with HCl to MgCl₂ (Mg²⁺ cation), not anion; inert with NaOH.
- C (2): Si (group 14, 3s² 3p²) forms acidic SiO₂; reacts with NaOH to [SiO₃]²⁻ but insoluble in HCl, no Cl-anion.
- D (3): P (group 15, 3s² 3p³) forms acidic P₄O₁₀; reacts with NaOH to [PO₄]³⁻ but with HCl yields H₃PO₄, no stable P-Cl anion.
Final answer: B
Topic: The Periodic Table: chemical periodicity
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