A Levels Chemistry (9701)•9701/13/M/J/20

Explanation
Electron configuration of Ni²⁺ by removing 4s electrons first Steps:
- Nickel (Ni) has atomic number 28, so neutral Ni has 28 electrons with configuration [Ar] 4s² 3d⁸ or 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁸.
- For transition metal cations like Ni²⁺, remove the two 4s electrons first due to higher energy of 4s orbital in ions.
- Ni²⁺ has 26 electrons, resulting in [Ar] 3d⁸.
- Full configuration: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸.
Why D is correct:
- D follows the rule that in transition metal ions, 4s electrons are removed before 3d, yielding [Ar] 3d⁸ per Aufbau principle adjusted for ions.
Why the others are wrong:
- A: Omits 2p⁶ and 3s² subshells, resulting in incomplete and incorrect filling.
- B: Includes 4s², representing neutral Ni (28 electrons) instead of Ni²⁺ (26 electrons).
- C: Lacks 3d electrons and has 4s⁰, giving only 18 electrons like argon, not Ni²⁺.
Final answer: D
Topic: Chemistry of transition elements
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